Physics and Chemistry of Finite Systems

This book covers studies on a wide range of materials, from clusters to nanostructures and quasicrystals, the emphasis being on understanding how the size-dependent properties change from discrete quantum conditions, as in nanoscale clusters, to bulk conditions that are insensitive to boundaries. The technological applications of clusters, nanoscale materials and quasicrystals are also addressed, including the nonlinear optical properties, mechanical behaviour, catalysis, cluster lamps, electronic devices and possible applications of fullerenes. The text deals with the following topics: preparation and characterization; atomic and molecular structure; stability and fragmentation; electronic, optical, magnetic and thermodynamic properties; molecular dynamics simulation; melting; cluster reactions and catalysis; cluster-support interaction; cluster assemblies; cluster involving C60 fullerenes; and technological applications.